Skip to content
DraconiticResearch
Search Sources API
193,349 studies31 sourcesUpdated 22 min ago
PreprintCC BY 4.0arXiv

Transient and universal regimes in quantum reaction-transport kinetics

Abstract

Quantum reaction-transport systems consist of coherently propagating particles that irreversibly react upon encounter. Their relaxation is commonly classified as reaction-limited or transport-limited, depending on the relative timescales of reaction and particle transport. We show that this expectation fails in low dimensions by studying the quantum binary annihilation, A+A → ∅, where reaction processes acquire singular fluctuation corrections below the upper critical dimension Dc=2. Consequently, fluctuations dominate the asymptotic kinetics for D<2. In one dimension, they render mean-field relaxation transient and drive the system toward a transport-limited regime with n∼ t−1/2, governed by a quantum-Zeno scale even for arbitrarily weak loss. At D=2, the kinetics acquires logarithmic corrections, whereas above two dimensions mean-field scaling is asymptotically restored. At and below the upper critical dimension, mean-field behavior can nevertheless persist over parametrically long crossover times before the asymptotic fluctuation-dominated regime emerges. We also show that the same fluctuations generate effective elastic collisions despite the absence of microscopic coherent interactions. In D>1, these collisions redistribute momentum populations and are parametrically faster than losses in the transport-limited regime, allowing the system to approach a quasi-stationary thermal state.

Related

  1. Operator-Level Description of Transient Thermal Grating Dynamics Across Transport Regimes
    Slobodanka Galovic, Steva Jacimovski
    arXivPreprintCC BY 4.0Full textApplied physics & instrumentationarXiv
  2. A computational study on the spin-forbidden reaction mechanism and kinetics of naphthalene with NH radical
    Rasoul Niazmand Liarjdameh, Shabnam Borji, Morteza Vahedpour
    Scientific ReportsPeer-reviewedCC BY-NC-ND 4.0Full textAtomic, molecular & optical physicsCrossref
  3. Universal mapping of drop impact spreading from wetting to Leidenfrost regimes
    Shushan Hu, Nan Hu, Zirui Li +3
    arXivPreprintCC BY 4.0Full textFluid dynamicsarXiv
  4. Universal model of the growth of III-V tetrahedral semiconductors on polar surfaces: pyramids and glue atoms. VII. Step kinetics
    Pawel Strak, Stanisław Krukowski
    arXivPreprintCC BY 4.0Full textCondensed matterarXiv
  5. First-Principles Study of I2 and CH3I Adsorption on Transition Metal Decorated 2D-Material substrates : Insights from Electronic Structure and Reaction Kinetics
    M. Meena, P. Anees
    arXivPreprintarXiv licenceFull textCondensed matterarXiv
BibTeX
@misc{hosseinabadi2026transient,
  title = {{Transient and universal regimes in quantum reaction-transport kinetics}},
  author = {Hossein Hosseinabadi and Roderich Moessner},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.09305},
  eprint = {2609.09305},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.09305},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Transient and universal regimes in quantum reaction-transport kinetics
AU  - Hossein Hosseinabadi
AU  - Roderich Moessner
PY  - 2026
DA  - 2026/09/08
PB  - arXiv
DO  - 10.48550/arxiv.2609.09305
UR  - https://arxiv.org/abs/2609.09305
AB  - Quantum reaction-transport systems consist of coherently propagating particles that irreversibly react upon encounter. Their relaxation is commonly classified as reaction-limited or transport-limited, depending on the relative timescales of reaction and particle transport. We show that this expectation fails in low dimensions by studying the quantum binary annihilation, A+A → ∅, where reaction processes acquire singular fluctuation corrections below the upper critical dimension D_c=2. Consequently, fluctuations dominate the asymptotic kinetics for D<2. In one dimension, they render mean-field relaxation transient and drive the system toward a transport-limited regime with n∼ t^−1/2, governed by a quantum-Zeno scale even for arbitrarily weak loss. At D=2, the kinetics acquires logarithmic corrections, whereas above two dimensions mean-field scaling is asymptotically restored. At and below the upper critical dimension, mean-field behavior can nevertheless persist over parametrically long crossover times before the asymptotic fluctuation-dominated regime emerges. We also show that the same fluctuations generate effective elastic collisions despite the absence of microscopic coherent interactions. In D>1, these collisions redistribute momentum populations and are parametrically faster than losses in the transport-limited regime, allowing the system to approach a quasi-stationary thermal state.
ER  -