Peer-reviewedCC BYActa crystallographica. Section E, Crystallographic communications
Occupational disorder of cobalt and indium in the crystal structure of Co₅In₃SbSi₂O₁₆.
- 1Institute for Chemical Technologies and Analytics, Division of Applied Solid State Chemistry, Getreidemarkt 9/E164-05-1, 1060 Vienna, Austria.
Abstract
Penta-cobalt(II) triindium(III) anti-mony(V) disilicon(VI) hexa-deca-oxide, Co5In3SbSi2O16, was obtained as a single-crystalline by-product through a reaction with the silica glass ampoule during a chemical vapor transport reaction. It crystallizes isotypically with Co8TeAs2O16 in space group Cmce, with two (out of four) Co sites co-occupied by In, the Te site replaced by Sb, and the As site replaced by Si. The crystal structure of Co5In3SbSi2O16 consists of [CoO6], [(In,Co)O6], and [SbO6] octa-hedra, and [CoO4] and [SiO4] tetra-hedra, fused by vertex- and edge-sharing into a complex three-dimensional framework.
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BibTeX
@article{wolflehner2026occupational,
title = {{Occupational disorder of cobalt and indium in the crystal structure of Co₅In₃SbSi₂O₁₆.}},
author = {Tobias Wolflehner and Matthias Weil},
journal = {Acta crystallographica. Section E, Crystallographic communications},
year = {2026},
month = oct,
doi = {10.1107/s2056989026010960},
url = {https://europepmc.org/article/MED/42997404},
note = {CC BY},
}
RIS
TY - JOUR
TI - Occupational disorder of cobalt and indium in the crystal structure of Co₅In₃SbSi₂O₁₆.
AU - Tobias Wolflehner
AU - Matthias Weil
PY - 2026
DA - 2026/10/23
JO - Acta crystallographica. Section E, Crystallographic communications
DO - 10.1107/s2056989026010960
UR - https://europepmc.org/article/MED/42997404
AB - Penta-cobalt(II) triindium(III) anti-mony(V) disilicon(VI) hexa-deca-oxide, Co5In3SbSi2O16, was obtained as a single-crystalline by-product through a reaction with the silica glass ampoule during a chemical vapor transport reaction. It crystallizes isotypically with Co8TeAs2O16 in space group Cmce, with two (out of four) Co sites co-occupied by In, the Te site replaced by Sb, and the As site replaced by Si. The crystal structure of Co5In3SbSi2O16 consists of [CoO6], [(In,Co)O6], and [SbO6] octa-hedra, and [CoO4] and [SiO4] tetra-hedra, fused by vertex- and edge-sharing into a complex three-dimensional framework.
SN - 2056-9890
ER -