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Peer-reviewedCC BY 4.0Polymers

A Sustainable Approach: Cellulose-Based Biodegradable Water-Retaining Agents Facilitating Mine Restoration in Arid Xinjiang Mining Zones

5 affiliations
  1. 1School of Chemical Engineering, Xinjiang University, Urumqi 830017, China
  2. 2Xinjiang Energy Co., Ltd., Urumqi 830026, China
  3. 3School of Chemical Engineering, Minhaj University Lahore, Lahore 54000, Pakistan
  4. 4Administration Committee of Chemical Industry Park, Midong District, Urumqi 831400, China
  5. 5School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China

Abstract

To address the poor biodegradability and high environmental risks of traditional synthetic water-retaining agents (WRAs), and the vegetation colonization challenge induced by organic matter deficiency in saline-alkali mining areas, a biodegradable WRA (CCM−CMC) was facilely synthesized from natural cellulose (CCM) and carboxymethyl cellulose (CMC) with epichlorohydrin (ECH) as a crosslinking agent. An in situ non-topsoil replacement remediation system of “superabsorbent polymer–biological fertilizer–native stress-tolerant plants” was established, and its water absorption-retention performance, biosafety, and ecological remediation efficacy were systematically evaluated. CCM−CMC displayed excellent equilibrium swelling ratios (1218, 443, 305, 148 g/g in distilled water, tap water, mining reclaimed water, and 0.9 wt% NaCl solution, respectively), with a 57.28% weight loss after 30-day soil burial, verifying favorable biodegradability. Soil application of CCM−CMC improved soil water-holding capacity by up to 39.20%, and maximally increased pakchoi germination rate, plant height, and dry weight by 23.33%, 327.4%, and 430.8% under drought stress. Field trials in Xinjiang arid mining areas achieved an over 80% survival rate for over ten native stress-tolerant plants, and significantly ameliorated the soil physicochemical properties. These eco-friendly WRAs and derived remediation technology avoid the high costs and ecological disturbance of topsoil replacement, providing a practical technical strategy for the ecological restoration of arid and highly saline-alkali mining areas.

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BibTeX
@article{li2026sustainable,
  title = {{A Sustainable Approach: Cellulose-Based Biodegradable Water-Retaining Agents Facilitating Mine Restoration in Arid Xinjiang Mining Zones}},
  author = {Kaigang Li and Naeem Akram and Lei Zhou and Zhanwen Cao and Huishan Zhang and Ali Ahmad and Zhenning Cheng and Aizong Wu and Wenlong Mo and Jia Guo},
  journal = {Polymers},
  year = {2026},
  month = oct,
  doi = {10.3390/polym18212670},
  url = {https://www.mdpi.com/2073-4360/18/21/2670},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - A Sustainable Approach: Cellulose-Based Biodegradable Water-Retaining Agents Facilitating Mine Restoration in Arid Xinjiang Mining Zones
AU  - Kaigang Li
AU  - Naeem Akram
AU  - Lei Zhou
AU  - Zhanwen Cao
AU  - Huishan Zhang
AU  - Ali Ahmad
AU  - Zhenning Cheng
AU  - Aizong Wu
AU  - Wenlong Mo
AU  - Jia Guo
PY  - 2026
DA  - 2026/10/28
JO  - Polymers
DO  - 10.3390/polym18212670
UR  - https://www.mdpi.com/2073-4360/18/21/2670
AB  - To address the poor biodegradability and high environmental risks of traditional synthetic water-retaining agents (WRAs), and the vegetation colonization challenge induced by organic matter deficiency in saline-alkali mining areas, a biodegradable WRA (CCM−CMC) was facilely synthesized from natural cellulose (CCM) and carboxymethyl cellulose (CMC) with epichlorohydrin (ECH) as a crosslinking agent. An in situ non-topsoil replacement remediation system of “superabsorbent polymer–biological fertilizer–native stress-tolerant plants” was established, and its water absorption-retention performance, biosafety, and ecological remediation efficacy were systematically evaluated. CCM−CMC displayed excellent equilibrium swelling ratios (1218, 443, 305, 148 g/g in distilled water, tap water, mining reclaimed water, and 0.9 wt% NaCl solution, respectively), with a 57.28% weight loss after 30-day soil burial, verifying favorable biodegradability. Soil application of CCM−CMC improved soil water-holding capacity by up to 39.20%, and maximally increased pakchoi germination rate, plant height, and dry weight by 23.33%, 327.4%, and 430.8% under drought stress. Field trials in Xinjiang arid mining areas achieved an over 80% survival rate for over ten native stress-tolerant plants, and significantly ameliorated the soil physicochemical properties. These eco-friendly WRAs and derived remediation technology avoid the high costs and ecological disturbance of topsoil replacement, providing a practical technical strategy for the ecological restoration of arid and highly saline-alkali mining areas.
SN  - 2073-4360
ER  -