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Peer-reviewedCC BY-NCRSC advances

Design and optimization of CdS-CeO₂ composite electrodes for enhanced electrochemical performance for asymmetric supercapacitors.

  1. 1School of Physics and Electronic Information, Yunnan Normal University 768, Juxian Street Kunming 650500 Yunnan China [email protected].
  2. 2Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University P. O. Box 84428 Riyadh 11671 Saudi Arabia.
  3. 3Department of Physics, Hazara University Mansehra 21300 Pakistan.

Abstract

The advance of high-performance energy storage devices (ESD) is critical for modern semiconductor technology, rechargeable vehicles, and renewable energy integration. In this work, a CdS-CeO₂ composite was successfully synthesized via a hydrothermal method and investigated as an electrode material for an asymmetric supercapacitor (ASCs). The CdS-CeO₂ composite leverages the high redox activity and structural stability of CeO₂ along with the enhanced electrical conductivity and charge transport of CdS. Structural and morphological characterization using XRD, BET surface analysis, SEM, and EDX mapping confirmed the formation of a well-dispersed, hierarchical composite with abundant electro active sites. Electrochemical measurements revealed that the CdS-CeO₂ electrode delivers a specific capacitance of 476 F g⁻¹ at 1 A g⁻¹, along with good rate performance and outstanding long-term stability, retaining 95.83% of its initial capacitance after 15 000 charge-discharge cycles. The asymmetric supercapacitor ASC (CdS-CeO₂//AC) exhibited a highest energy density of 57.74 Wh kg⁻¹, and power density of 6298 W kg⁻¹, indicating the effectiveness of the CdS incorporation in enhancing the electrochemical performance. These results highlight the potential of oxide-sulfide composite engineering in designing next-generation electrodes for high-performance ASCs.

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BibTeX
@article{riaz2026design,
  title = {{Design and optimization of CdS-CeO₂ composite electrodes for enhanced electrochemical performance for asymmetric supercapacitors.}},
  author = {Junaid Riaz and Muhammad Arif and Samira Elaissi and Amina Bibi},
  journal = {RSC advances},
  year = {2026},
  month = oct,
  doi = {10.1039/d6ra07046a},
  url = {https://europepmc.org/article/MED/42836151},
  note = {CC BY-NC},
}
RIS
TY  - JOUR
TI  - Design and optimization of CdS-CeO₂ composite electrodes for enhanced electrochemical performance for asymmetric supercapacitors.
AU  - Junaid Riaz
AU  - Muhammad Arif
AU  - Samira Elaissi
AU  - Amina Bibi
PY  - 2026
DA  - 2026/10/05
JO  - RSC advances
DO  - 10.1039/d6ra07046a
UR  - https://europepmc.org/article/MED/42836151
AB  - The advance of high-performance energy storage devices (ESD) is critical for modern semiconductor technology, rechargeable vehicles, and renewable energy integration. In this work, a CdS-CeO₂ composite was successfully synthesized via a hydrothermal method and investigated as an electrode material for an asymmetric supercapacitor (ASCs). The CdS-CeO₂ composite leverages the high redox activity and structural stability of CeO₂ along with the enhanced electrical conductivity and charge transport of CdS. Structural and morphological characterization using XRD, BET surface analysis, SEM, and EDX mapping confirmed the formation of a well-dispersed, hierarchical composite with abundant electro active sites. Electrochemical measurements revealed that the CdS-CeO₂ electrode delivers a specific capacitance of 476 F g⁻¹ at 1 A g⁻¹, along with good rate performance and outstanding long-term stability, retaining 95.83% of its initial capacitance after 15 000 charge-discharge cycles. The asymmetric supercapacitor ASC (CdS-CeO₂//AC) exhibited a highest energy density of 57.74 Wh kg⁻¹, and power density of 6298 W kg⁻¹, indicating the effectiveness of the CdS incorporation in enhancing the electrochemical performance. These results highlight the potential of oxide-sulfide composite engineering in designing next-generation electrodes for high-performance ASCs.
SN  - 2046-2069
ER  -