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Peer-reviewedCC BYDiamond and Related Materials

The effect of nitrogen implantation on resistive switching of tetrahedral amorphous carbon films

Abstract

We report the effect of nitrogen implantation on the resistance switching of tetrahedral amorphous carbon (ta-C) films. Both unimplanted and implanted films show resistive switching, with a characteristic threshold voltage required to switch the films from the high-resistance to the low-resistance state. The switching voltages for the unimplanted films are between 7 and 10 V for ta-C films of thickness 15 to 40 nm. These are significantly reduced upon implantation by up to 60% when using an implantation dose ~3 × 1015 cm−2. We attribute this to increased sp2 bonding and clustering in the implanted films. This demonstrates the importance of sp2 clustering for resistive-switching in sp3-rich ta-C films.

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BibTeX
@article{nagareddy2026effect,
  title = {{The effect of nitrogen implantation on resistive switching of tetrahedral amorphous carbon films}},
  author = {V.K. Nagareddy and A.K. Ott and C. Dou and T. Tsvetkova and M. Sandulov and M.F. Craciun and A.C. Ferrari and C.D. Wright},
  journal = {Diamond and Related Materials},
  year = {2026},
  month = sep,
  doi = {10.1016/j.diamond.2018.05.005},
  url = {https://hal.science/hal-04650124v1},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - The effect of nitrogen implantation on resistive switching of tetrahedral amorphous carbon films
AU  - V.K. Nagareddy
AU  - A.K. Ott
AU  - C. Dou
AU  - T. Tsvetkova
AU  - M. Sandulov
AU  - M.F. Craciun
AU  - A.C. Ferrari
AU  - C.D. Wright
PY  - 2026
DA  - 2026/09/01
JO  - Diamond and Related Materials
DO  - 10.1016/j.diamond.2018.05.005
UR  - https://hal.science/hal-04650124v1
AB  - We report the effect of nitrogen implantation on the resistance switching of tetrahedral amorphous carbon (ta-C) films. Both unimplanted and implanted films show resistive switching, with a characteristic threshold voltage required to switch the films from the high-resistance to the low-resistance state. The switching voltages for the unimplanted films are between 7 and 10 V for ta-C films of thickness 15 to 40 nm. These are significantly reduced upon implantation by up to 60% when using an implantation dose ~3 × 1015 cm−2. We attribute this to increased sp2 bonding and clustering in the implanted films. This demonstrates the importance of sp2 clustering for resistive-switching in sp3-rich ta-C films.
SN  - 0925-9635
ER  -