A core-level electron spectroscopy study of gas-phase 1,2,3-benzotriazole and methyl derivatives
Abstract
A gas-phase photoelectron spectroscopy and X-ray absorption spectroscopy study of 1,2,3-benzotriazole and methyl derivatives was undertaken to investigate the influence of the tautomerism on the spectroscopic signature in greater detail. Soft X-ray photoelectron spectroscopy of the nitrogen core level, nitrogen K-edge near-edge X-ray absorption fine-structure measurements, and mapping of the resonant Auger spectroscopy were performed. High-energy ultraviolet photoemission spectroscopy was also undertaken to compare with the previous studies using low-energy low-energy Helium I and Helium II excitation. The gas-phase characterization is an essential step for interpreting adsorbed molecular phases and thin films on surfaces. The results also served as a test of STOBE density functional theory calculations, in particular the near edge.
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BibTeX
@article{bolke2026corelevel,
title = {{A core-level electron spectroscopy study of gas-phase 1,2,3-benzotriazole and methyl derivatives}},
author = {Sven Bölke and Christophe Nicolas and John Bozek and Heiko Peisert and David Batchelor},
journal = {Beilstein Journal of Nanotechnology},
year = {2026},
month = sep,
doi = {10.3762/bjnano.17.88},
url = {https://hal.science/hal-05797565v1},
note = {CC BY},
}
RIS
TY - JOUR
TI - A core-level electron spectroscopy study of gas-phase 1,2,3-benzotriazole and methyl derivatives
AU - Sven Bölke
AU - Christophe Nicolas
AU - John Bozek
AU - Heiko Peisert
AU - David Batchelor
PY - 2026
DA - 2026/09/18
JO - Beilstein Journal of Nanotechnology
DO - 10.3762/bjnano.17.88
UR - https://hal.science/hal-05797565v1
AB - A gas-phase photoelectron spectroscopy and X-ray absorption spectroscopy study of 1,2,3-benzotriazole and methyl derivatives was undertaken to investigate the influence of the tautomerism on the spectroscopic signature in greater detail. Soft X-ray photoelectron spectroscopy of the nitrogen core level, nitrogen K-edge near-edge X-ray absorption fine-structure measurements, and mapping of the resonant Auger spectroscopy were performed. High-energy ultraviolet photoemission spectroscopy was also undertaken to compare with the previous studies using low-energy low-energy Helium I and Helium II excitation. The gas-phase characterization is an essential step for interpreting adsorbed molecular phases and thin films on surfaces. The results also served as a test of STOBE density functional theory calculations, in particular the near edge.
SN - 2190-4286
ER -