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PreprintCC BY 4.0arXiv

Characterizing the functional role of quantum coherence in energy transfer

Abstract

Quantum coherence has been suggested to play a role in excitation energy transfer in open quantum systems, yet a quantitative approach to assessing its influence on the transfer process is still missing. Using Nakajima-Zwanzig projection operators, we derive a general memory kernel identity that enables us to characterize and quantify the impact of coherence in the eigenenergy basis on a generalized rate of energy transfer. Applying our approach to the electronic dynamics of a dimer coupled to a structured phonon bath, we demonstrate how quantum coherence acts to modulate energy transfer.

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BibTeX
@misc{gestsson2026characterizing,
  title = {{Characterizing the functional role of quantum coherence in energy transfer}},
  author = {Hallmann Óskar Gestsson and Alexandra Olaya-Castro},
  howpublished = {arXiv},
  year = {2026},
  month = oct,
  doi = {10.48550/arxiv.2606.13404},
  eprint = {2606.13404},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2606.13404},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Characterizing the functional role of quantum coherence in energy transfer
AU  - Hallmann Óskar Gestsson
AU  - Alexandra Olaya-Castro
PY  - 2026
DA  - 2026/10/13
PB  - arXiv
DO  - 10.48550/arxiv.2606.13404
UR  - https://arxiv.org/abs/2606.13404
AB  - Quantum coherence has been suggested to play a role in excitation energy transfer in open quantum systems, yet a quantitative approach to assessing its influence on the transfer process is still missing. Using Nakajima-Zwanzig projection operators, we derive a general memory kernel identity that enables us to characterize and quantify the impact of coherence in the eigenenergy basis on a generalized rate of energy transfer. Applying our approach to the electronic dynamics of a dimer coupled to a structured phonon bath, we demonstrate how quantum coherence acts to modulate energy transfer.
ER  -