PreprintCC BY 4.0arXiv
Characterizing the functional role of quantum coherence in energy transfer
Abstract
Quantum coherence has been suggested to play a role in excitation energy transfer in open quantum systems, yet a quantitative approach to assessing its influence on the transfer process is still missing. Using Nakajima-Zwanzig projection operators, we derive a general memory kernel identity that enables us to characterize and quantify the impact of coherence in the eigenenergy basis on a generalized rate of energy transfer. Applying our approach to the electronic dynamics of a dimer coupled to a structured phonon bath, we demonstrate how quantum coherence acts to modulate energy transfer.
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BibTeX
@misc{gestsson2026characterizing,
title = {{Characterizing the functional role of quantum coherence in energy transfer}},
author = {Hallmann Óskar Gestsson and Alexandra Olaya-Castro},
howpublished = {arXiv},
year = {2026},
month = oct,
doi = {10.48550/arxiv.2606.13404},
eprint = {2606.13404},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2606.13404},
note = {CC BY 4.0},
}
RIS
TY - UNPB
TI - Characterizing the functional role of quantum coherence in energy transfer
AU - Hallmann Óskar Gestsson
AU - Alexandra Olaya-Castro
PY - 2026
DA - 2026/10/13
PB - arXiv
DO - 10.48550/arxiv.2606.13404
UR - https://arxiv.org/abs/2606.13404
AB - Quantum coherence has been suggested to play a role in excitation energy transfer in open quantum systems, yet a quantitative approach to assessing its influence on the transfer process is still missing. Using Nakajima-Zwanzig projection operators, we derive a general memory kernel identity that enables us to characterize and quantify the impact of coherence in the eigenenergy basis on a generalized rate of energy transfer. Applying our approach to the electronic dynamics of a dimer coupled to a structured phonon bath, we demonstrate how quantum coherence acts to modulate energy transfer.
ER -