Design and Optimization of Bottom-Hole Temperature–Pressure Combinations in Gas Production from Gas Hydrates via Carbon Dioxide Replacement Strategy
4 affiliations
- 1School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China
- 2Faculty of Engineering, China University of Petroleum-Beijing at Karamay, Karamay 834000, China
- 3School of Energy Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China
- 4School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China
Abstract
Carbon dioxide replacement represents a promising hydrate development strategy that effectively balances production efficiency and environmental considerations. However, its production efficiency is lower than that of the depressurization strategy. This limitation can be effectively alleviated by coupling carbon dioxide replacement with inhibitor injection. The design and optimization of the temperature–pressure operating window constrain its effective implementation. In the present work, the phase equilibrium conditions of carbon dioxide hydrate and methane hydrate were experimentally investigated. It was found that the experimental values obtained in this study are in excellent agreement with those calculated by the CSMHyd program. The average absolute relative deviations (AARD) for the experimental versus calculated results are 5.77% for methane hydrate and 2.66% for carbon dioxide hydrate. Then, the methodology for determining the recommended temperature–pressure combinations used in the carbon dioxide replacement strategy was proposed, and the size of region in which these combinations occur was quantified. The investigation results found that there are significant differences in the size of the recommended region for different sea areas, and inhibitor injection reduces the size of this recommended region. Injection of 3.0 wt% NaCl solution reduces the size of recommended region from 10.968 K·MPa to 8.366 K·MPa for pure methane hydrate, and a similar trend is also observed for natural gas hydrates. Based on the experimental results, the carbon sequestration potential of natural gas hydrate development using the carbon dioxide replacement strategy on core size was analyzed. The final simulation results show that 9.05 mol of carbon dioxide hydrate was obtained in the reaction vessel, which achieves effective CO2 sequestration. The investigation in this work provides theoretical support for dual goals of carbon sequestration and efficient gas production from gas hydrates.
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BibTeX
@article{wu2026design,
title = {{Design and Optimization of Bottom-Hole Temperature–Pressure Combinations in Gas Production from Gas Hydrates via Carbon Dioxide Replacement Strategy}},
author = {Jingjuan Wu and Qi Li and Qingchao Li and Fuling Wang and Yuanfang Cheng and Chuanliang Yan},
journal = {Energies},
year = {2026},
month = jul,
doi = {10.3390/en19153536},
url = {https://doi.org/10.3390/en19153536},
note = {CC BY},
}
RIS
TY - JOUR
TI - Design and Optimization of Bottom-Hole Temperature–Pressure Combinations in Gas Production from Gas Hydrates via Carbon Dioxide Replacement Strategy
AU - Jingjuan Wu
AU - Qi Li
AU - Qingchao Li
AU - Fuling Wang
AU - Yuanfang Cheng
AU - Chuanliang Yan
PY - 2026
DA - 2026/07/27
JO - Energies
DO - 10.3390/en19153536
UR - https://doi.org/10.3390/en19153536
AB - Carbon dioxide replacement represents a promising hydrate development strategy that effectively balances production efficiency and environmental considerations. However, its production efficiency is lower than that of the depressurization strategy. This limitation can be effectively alleviated by coupling carbon dioxide replacement with inhibitor injection. The design and optimization of the temperature–pressure operating window constrain its effective implementation. In the present work, the phase equilibrium conditions of carbon dioxide hydrate and methane hydrate were experimentally investigated. It was found that the experimental values obtained in this study are in excellent agreement with those calculated by the CSMHyd program. The average absolute relative deviations (AARD) for the experimental versus calculated results are 5.77% for methane hydrate and 2.66% for carbon dioxide hydrate. Then, the methodology for determining the recommended temperature–pressure combinations used in the carbon dioxide replacement strategy was proposed, and the size of region in which these combinations occur was quantified. The investigation results found that there are significant differences in the size of the recommended region for different sea areas, and inhibitor injection reduces the size of this recommended region. Injection of 3.0 wt% NaCl solution reduces the size of recommended region from 10.968 K·MPa to 8.366 K·MPa for pure methane hydrate, and a similar trend is also observed for natural gas hydrates. Based on the experimental results, the carbon sequestration potential of natural gas hydrate development using the carbon dioxide replacement strategy on core size was analyzed. The final simulation results show that 9.05 mol of carbon dioxide hydrate was obtained in the reaction vessel, which achieves effective CO2 sequestration. The investigation in this work provides theoretical support for dual goals of carbon sequestration and efficient gas production from gas hydrates.
SN - 1996-1073
ER -