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Peer-reviewedCC BY-NC-ND 4.0Advanced Synthesis and Catalysis

1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications

  • Jayaram Vankudoth
  • Maruti Mali
  • Fabienne Berrée
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Abstract

In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to CC, C‐heteroatom, and multicomponent products. The study covers both symmetrical and unsymmetrical strategies for synthesizing bis(boronates) from alkenes, alkynes, and carbonyl precursors, including metal‐catalyzed, base‐promoted, and organophosphorus‐mediated methods. In addition to demonstrating their versatility in building complex molecular frameworks for medicinal chemistry, alkenyl bis(boronates) are used in regioselective transformations. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and 1,2‐alkenyl bis(boronate) compounds.

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Cite

BibTeXRIS
BibTeX
@article{vankudoth202611and,
  title = {{1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications}},
  author = {Jayaram Vankudoth and Maruti Mali and Fabienne Berrée},
  journal = {Advanced Synthesis and Catalysis},
  year = {2026},
  month = jun,
  doi = {10.1002/adsc.70423},
  url = {https://hal.science/hal-05676070v1},
  note = {CC BY-NC-ND 4.0},
}
RIS
TY  - JOUR
TI  - 1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications
AU  - Jayaram Vankudoth
AU  - Maruti Mali
AU  - Fabienne Berrée
PY  - 2026
DA  - 2026/06/08
JO  - Advanced Synthesis and Catalysis
DO  - 10.1002/adsc.70423
UR  - https://hal.science/hal-05676070v1
AB  - In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to CC, C‐heteroatom, and multicomponent products. The study covers both symmetrical and unsymmetrical strategies for synthesizing bis(boronates) from alkenes, alkynes, and carbonyl precursors, including metal‐catalyzed, base‐promoted, and organophosphorus‐mediated methods. In addition to demonstrating their versatility in building complex molecular frameworks for medicinal chemistry, alkenyl bis(boronates) are used in regioselective transformations. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and 1,2‐alkenyl bis(boronate) compounds.
SN  - 1615-4150
SN  - 1615-4169
ER  -