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PreprintCC BYChemRxiv

A PN adamantanoid ligand for reticular materials

  • Pinelopi A. Tsami1
  • Ethan Trenaman1
  • Anjali Nambidiyattil1
  • Mohsen Shayan2
  • Saurabh S. Chitnis1,2
  1. 1Department of Chemistry, University of Victoria, 4800 Finnerty Road, Victoria, BC, Canada, V8P 5C2
  2. 2Department of Chemistry, Dalhousie University, 6243 Alumni Crescent, Halifax, NS, Canada, B3H 4R2
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Abstract

Three dimensional linkers are rare in MOF chemistry, as are linkers featuring inorganic elements. Here we report the synthesis and characterisation of a novel phosphorus-nitrogen (PN) cage-based tetra-benzoic acid (P4BA4) and its use for the synthesis of crystalline framework materials PNMOF-1 and PNHOF-1. These results expand the toolkit of 3-dimensional inorganic linkers beyond the current state of the art defined by carboranes and silsequioxanes.

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Cite

BibTeXRIS
BibTeX
@misc{tsami2026adamantanoid,
  title = {{A PN adamantanoid ligand for reticular materials}},
  author = {Pinelopi A. Tsami and Ethan Trenaman and Anjali Nambidiyattil and Mohsen Shayan and Saurabh S. Chitnis},
  howpublished = {ChemRxiv},
  year = {2026},
  month = sep,
  doi = {10.26434/chemrxiv.15009518/v1},
  url = {https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009518/v1},
  note = {CC BY},
}
RIS
TY  - UNPB
TI  - A PN adamantanoid ligand for reticular materials
AU  - Pinelopi A. Tsami
AU  - Ethan Trenaman
AU  - Anjali Nambidiyattil
AU  - Mohsen Shayan
AU  - Saurabh S. Chitnis
PY  - 2026
DA  - 2026/09/28
PB  - ChemRxiv
DO  - 10.26434/chemrxiv.15009518/v1
UR  - https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009518/v1
AB  - Three dimensional linkers are rare in MOF chemistry, as are linkers featuring inorganic elements. Here we report the synthesis and characterisation of a novel phosphorus-nitrogen (PN) cage-based tetra-benzoic acid (P4BA4) and its use for the synthesis of crystalline framework materials PNMOF-1 and PNHOF-1. These results expand the toolkit of 3-dimensional inorganic linkers beyond the current state of the art defined by carboranes and silsequioxanes.
ER  -