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Peer-reviewedCC BYIUCrData

3-[(2-Chloro-eth-oxy)carbon-yl]-7-oxabi-cyclo-[2.2.1]heptane-2-carb-oxy-lic acid.

  • Hannah K Lawley1
  • Noah K Archer1
  • Bailey N Baxter1
  • Madeline R Borchert1
  • Grace E Lewis1
  • Mary Helene Marmande1
  • Kathryn N Mayeaux1
  • Lucy A Orr1
  • Matthias Zeller2
  • David C Forbes1
  1. 1University of South Alabama, Department of Chemistry 6040 USA Drive South Mobile Alabama 36608 USA.
  2. 2Purdue University, Department of Chemistry, 560 Oval Drive, West Lafayette, Indiana 47907, USA.
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Abstract

The structure of the title compound, C10H13ClO5, was obtained by anhydride ring opening of norcantharidin with chloro-ethanol and pyridine as base. The title compound has triclinic (P1) symmetry, with individual mol-ecules connected via their carb-oxy-lic acid groups into centrosymmetric dimers. Additional C-H⋯O inter-actions connect these dimers into slabs parallel to the ab plane (001). Steric crowding between the carb-oxy-lic acid and ester moieties leads to a strained C-C-C angle involving the ester carbon atom.

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Cite

BibTeXRIS
BibTeX
@article{lawley202632chloroethoxycarbonyl7oxabicyclo221heptane2carboxylic,
  title = {{3-[(2-Chloro-eth-oxy)carbon-yl]-7-oxabi-cyclo-[2.2.1]heptane-2-carb-oxy-lic acid.}},
  author = {Hannah K Lawley and Noah K Archer and Bailey N Baxter and Madeline R Borchert and Grace E Lewis and Mary Helene Marmande and Kathryn N Mayeaux and Lucy A Orr and Matthias Zeller and David C Forbes},
  journal = {IUCrData},
  year = {2026},
  month = sep,
  doi = {10.1107/s2414314626011211},
  url = {https://europepmc.org/article/MED/42997373},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - 3-[(2-Chloro-eth-oxy)carbon-yl]-7-oxabi-cyclo-[2.2.1]heptane-2-carb-oxy-lic acid.
AU  - Hannah K Lawley
AU  - Noah K Archer
AU  - Bailey N Baxter
AU  - Madeline R Borchert
AU  - Grace E Lewis
AU  - Mary Helene Marmande
AU  - Kathryn N Mayeaux
AU  - Lucy A Orr
AU  - Matthias Zeller
AU  - David C Forbes
PY  - 2026
DA  - 2026/09/01
JO  - IUCrData
DO  - 10.1107/s2414314626011211
UR  - https://europepmc.org/article/MED/42997373
AB  - The structure of the title compound, C10H13ClO5, was obtained by anhydride ring opening of norcantharidin with chloro-ethanol and pyridine as base. The title compound has triclinic (P1) symmetry, with individual mol-ecules connected via their carb-oxy-lic acid groups into centrosymmetric dimers. Additional C-H⋯O inter-actions connect these dimers into slabs parallel to the ab plane (001). Steric crowding between the carb-oxy-lic acid and ester moieties leads to a strained C-C-C angle involving the ester carbon atom.
SN  - 2414-3146
ER  -