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Peer-reviewedCC BY-NC-ND 4.0ARKIVOC - Online Journal of Organic Chemistry

Electrochemical functionalization of allylic amines: a straightforward route to relevant aza-compounds

  • Aurélie Claraz
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Abstract

Allylic amines are versatile building blocks in organic synthesis that can be readily transformed into relevant azacompounds through functionalization of the carbon-carbon double bond. Practical electrochemical approaches offer the advantage of operating under mild, safe, eco-friendly, and cost-effective conditions. This short review summarizes advances in the electricity-enabled functionalization of allylic amines, with particular emphasis on mechanistic insights. It highlights the synthesis of valuable azacycles and β-arylethylamines. Finally, future directions are discussed to inspire synthetic chemists to pursue increasingly complex nitrogencontaining architectures via electrochemical functionalization of allylic amines.

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Cite

BibTeXRIS
BibTeX
@article{claraz2026electrochemical,
  title = {{Electrochemical functionalization of allylic amines: a straightforward route to relevant aza-compounds}},
  author = {Aurélie Claraz},
  journal = {ARKIVOC - Online Journal of Organic Chemistry},
  year = {2026},
  month = oct,
  doi = {10.24820/ark.5550190.p012.576},
  url = {https://hal.science/hal-05838316v1},
  note = {CC BY-NC-ND 4.0},
}
RIS
TY  - JOUR
TI  - Electrochemical functionalization of allylic amines: a straightforward route to relevant aza-compounds
AU  - Aurélie Claraz
PY  - 2026
DA  - 2026/10/26
JO  - ARKIVOC - Online Journal of Organic Chemistry
DO  - 10.24820/ark.5550190.p012.576
UR  - https://hal.science/hal-05838316v1
AB  - Allylic amines are versatile building blocks in organic synthesis that can be readily transformed into relevant azacompounds through functionalization of the carbon-carbon double bond. Practical electrochemical approaches offer the advantage of operating under mild, safe, eco-friendly, and cost-effective conditions. This short review summarizes advances in the electricity-enabled functionalization of allylic amines, with particular emphasis on mechanistic insights. It highlights the synthesis of valuable azacycles and β-arylethylamines. Finally, future directions are discussed to inspire synthetic chemists to pursue increasingly complex nitrogencontaining architectures via electrochemical functionalization of allylic amines.
SN  - 1551-7004
SN  - 1551-7012
ER  -