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PreprintCC BYChemRxiv

Toward bio-circular, fully organic batteries from non-toxic and bio-derived materials

Abstract

The development of biodegradable energy storage systems is essential for enabling environmental monitoring devices that can degrade after stable operation. In this work, we present a fully organic, bio-circular battery that uses materials selected using a framework based on their natural occurrence and hazard classification according to the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). We use redox-active organic molecules, aloe-emodin and luteolin, immobilized on activated coconut charcoal, together with an agarose/carboxymethyl cellulose gel polymer electrolyte and current collectors based on graphite flakes, carbon black, and agarose. The resulting battery delivers 0.7 V and stable electrochemical performance, supplying 8.8 mAh/g after 200 cycles, with 73.6% capacity retention and 98% coulombic efficiency. All components are further integrated into a pouch cell with an agarose packaging and beeswax coating. This prototype exhibits a discharge capacity of 7.1 μAh and 77.9% capacity retention over 20 cycles. Under simulated aerobic composting conditions, the pouch cell shows rapid and substantial disintegration, highlighting its potential for environmentally benign end-of-life scenarios. This work establishes a comprehensive design strategy for bio-circular batteries and demonstrates the applicability of bio-derived, GHS-non-toxic, fully organic materials for sustainable energy storage solutions.

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BibTeX
@misc{michel2026toward,
  title = {{Toward bio-circular, fully organic batteries from non-toxic and bio-derived materials}},
  author = {Veronica F. Michel and Tina Curtins and Oliver von Grünigen and Markus Niederberger},
  howpublished = {ChemRxiv},
  year = {2026},
  month = oct,
  doi = {10.26434/chemrxiv.15006763/v2},
  url = {https://chemrxiv.org/doi/full/10.26434/chemrxiv.15006763/v2},
  note = {CC BY},
}
RIS
TY  - UNPB
TI  - Toward bio-circular, fully organic batteries from non-toxic and bio-derived materials
AU  - Veronica F. Michel
AU  - Tina Curtins
AU  - Oliver von Grünigen
AU  - Markus Niederberger
PY  - 2026
DA  - 2026/10/12
PB  - ChemRxiv
DO  - 10.26434/chemrxiv.15006763/v2
UR  - https://chemrxiv.org/doi/full/10.26434/chemrxiv.15006763/v2
AB  - The development of biodegradable energy storage systems is essential for enabling environmental monitoring devices that can degrade after stable operation. In this work, we present a fully organic, bio-circular battery that uses materials selected using a framework based on their natural occurrence and hazard classification according to the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). We use redox-active organic molecules, aloe-emodin and luteolin, immobilized on activated coconut charcoal, together with an agarose/carboxymethyl cellulose gel polymer electrolyte and current collectors based on graphite flakes, carbon black, and agarose. The resulting battery delivers 0.7 V and stable electrochemical performance, supplying 8.8 mAh/g after 200 cycles, with 73.6% capacity retention and 98% coulombic efficiency. All components are further integrated into a pouch cell with an agarose packaging and beeswax coating. This prototype exhibits a discharge capacity of 7.1 μAh and 77.9% capacity retention over 20 cycles. Under simulated aerobic composting conditions, the pouch cell shows rapid and substantial disintegration, highlighting its potential for environmentally benign end-of-life scenarios. This work establishes a comprehensive design strategy for bio-circular batteries and demonstrates the applicability of bio-derived, GHS-non-toxic, fully organic materials for sustainable energy storage solutions.
ER  -