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PreprintCC BY 4.0EarthArXiv

Satellite-Based CO and NOx Emission Estimates from South-Central Chilean Plantation Fires

Abstract

We present top-down CO and NOx emission estimates for a south-central Chilean fire from Sentinel-5P/TROPOMI observations. Applying the Cross-Sectional Flux method to CO and the Exponentially Modified Gaussian method to NO2, with uncertainty propagated through 500-member Monte Carlo ensembles, we retrieve a median CO flux of 1,273 kg s⁻¹ (95% CI: 676–1,843 kg s⁻¹) and a median NOx flux of 7,505 g s⁻¹ (95% CI: 3,620–9,655 g s⁻¹) on the peak fire day. Against the hourly Copernicus Atmosphere Monitoring Service Global Fire Assimilation System (GFAS) inventory, the top-down median CO flux is 21 times GFAS for the overpass hour and 4.1 times its local-day mean. The top-down NOx flux is 2.4 times GFAS at the overpass hour but 52% below its local-day mean, and the retrieved CO:NOx ratio is 8.5–8.7 times the GFAS ratio in both cases. GFAS sets its ratio with generic extratropical-forest and savanna emission factors; its forest NOx emission factor is 2.5 times a TROPOMI-derived temperate-forest value. To map the region affected by the smoke, we drove a Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) forward dispersion simulation with the retrieved CO flux: the plume traveled more than 2,000 km north-northwestward within 96 hours, along the Chilean coast and over the subtropical southeast Pacific, where TROPOMI observed enhanced CO.

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BibTeX
@misc{perezcarrasco2026satellitebased,
  title = {{Satellite-Based CO and NOx Emission Estimates from South-Central Chilean Plantation Fires}},
  author = {Manuel Perez-Carrasco and Qindan Zhu and Cecilia Garraffo and Xiong Liu and Jia Chen},
  howpublished = {EarthArXiv},
  year = {2026},
  month = oct,
  doi = {10.31223/x5q812},
  url = {https://eartharxiv.org/repository/view/15693/},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Satellite-Based CO and NOx Emission Estimates from South-Central Chilean Plantation Fires
AU  - Manuel Perez-Carrasco
AU  - Qindan Zhu
AU  - Cecilia Garraffo
AU  - Xiong Liu
AU  - Jia Chen
PY  - 2026
DA  - 2026/10/23
PB  - EarthArXiv
DO  - 10.31223/x5q812
UR  - https://eartharxiv.org/repository/view/15693/
AB  - We present top-down CO and NOx emission estimates for a south-central Chilean fire from Sentinel-5P/TROPOMI observations. Applying the Cross-Sectional Flux method to CO and the Exponentially Modified Gaussian method to NO2, with uncertainty propagated through 500-member Monte Carlo ensembles, we retrieve a median CO flux of 1,273 kg s⁻¹ (95% CI: 676–1,843 kg s⁻¹) and a median NOx flux of 7,505 g s⁻¹ (95% CI: 3,620–9,655 g s⁻¹) on the peak fire day. Against the hourly Copernicus Atmosphere Monitoring Service Global Fire Assimilation System (GFAS) inventory, the top-down median CO flux is 21 times GFAS for the overpass hour and 4.1 times its local-day mean. The top-down NOx flux is 2.4 times GFAS at the overpass hour but 52% below its local-day mean, and the retrieved CO:NOx ratio is 8.5–8.7 times the GFAS ratio in both cases. GFAS sets its ratio with generic extratropical-forest and savanna emission factors; its forest NOx emission factor is 2.5 times a TROPOMI-derived temperate-forest value. To map the region affected by the smoke, we drove a Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) forward dispersion simulation with the retrieved CO flux: the plume traveled more than 2,000 km north-northwestward within 96 hours, along the Chilean coast and over the subtropical southeast Pacific, where TROPOMI observed enhanced CO.
ER  -