PreprintCC BY 4.0arXiv
Graphene-enabled dynamic H-J switching of dipole-dipole coupling
Abstract
Environmental modification of dipole interactions has long been explored in energy transport. Here we consider the effects of a tunable graphene monolayer upon nearly H-type or J-type molecular aggregates, concentrating on the inversion of one type of coupling to the other. Modelling the graphene as being deposited on a metallic substrate, we find that as the surface conductivity of the graphene is varied, there is a corresponding change in the parameter region over which coupling inversion is predicted. This provides a route towards observing the predicted coupling inversion in a real system by dynamically changing the surface conductivity during a single run of an experiment.
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BibTeX
@misc{mcfadden2026grapheneenabled,
title = {{Graphene-enabled dynamic H-J switching of dipole-dipole coupling}},
author = {Michael McFadden and Robert Bennett},
howpublished = {arXiv},
year = {2026},
month = sep,
doi = {10.48550/arxiv.2609.02933},
eprint = {2609.02933},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2609.02933},
note = {CC BY 4.0},
}
RIS
TY - UNPB
TI - Graphene-enabled dynamic H-J switching of dipole-dipole coupling
AU - Michael McFadden
AU - Robert Bennett
PY - 2026
DA - 2026/09/01
PB - arXiv
DO - 10.48550/arxiv.2609.02933
UR - https://arxiv.org/abs/2609.02933
AB - Environmental modification of dipole interactions has long been explored in energy transport. Here we consider the effects of a tunable graphene monolayer upon nearly H-type or J-type molecular aggregates, concentrating on the inversion of one type of coupling to the other. Modelling the graphene as being deposited on a metallic substrate, we find that as the surface conductivity of the graphene is varied, there is a corresponding change in the parameter region over which coupling inversion is predicted. This provides a route towards observing the predicted coupling inversion in a real system by dynamically changing the surface conductivity during a single run of an experiment.
ER -