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PreprintCC BY 4.0arXiv

Graphene-enabled dynamic H-J switching of dipole-dipole coupling

Abstract

Environmental modification of dipole interactions has long been explored in energy transport. Here we consider the effects of a tunable graphene monolayer upon nearly H-type or J-type molecular aggregates, concentrating on the inversion of one type of coupling to the other. Modelling the graphene as being deposited on a metallic substrate, we find that as the surface conductivity of the graphene is varied, there is a corresponding change in the parameter region over which coupling inversion is predicted. This provides a route towards observing the predicted coupling inversion in a real system by dynamically changing the surface conductivity during a single run of an experiment.

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BibTeX
@misc{mcfadden2026grapheneenabled,
  title = {{Graphene-enabled dynamic H-J switching of dipole-dipole coupling}},
  author = {Michael McFadden and Robert Bennett},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.02933},
  eprint = {2609.02933},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.02933},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Graphene-enabled dynamic H-J switching of dipole-dipole coupling
AU  - Michael McFadden
AU  - Robert Bennett
PY  - 2026
DA  - 2026/09/01
PB  - arXiv
DO  - 10.48550/arxiv.2609.02933
UR  - https://arxiv.org/abs/2609.02933
AB  - Environmental modification of dipole interactions has long been explored in energy transport. Here we consider the effects of a tunable graphene monolayer upon nearly H-type or J-type molecular aggregates, concentrating on the inversion of one type of coupling to the other. Modelling the graphene as being deposited on a metallic substrate, we find that as the surface conductivity of the graphene is varied, there is a corresponding change in the parameter region over which coupling inversion is predicted. This provides a route towards observing the predicted coupling inversion in a real system by dynamically changing the surface conductivity during a single run of an experiment.
ER  -