Skip to content
DraconiticResearch
Search Sources API
203,203 studies31 sourcesUpdated 10 min ago
Peer-reviewedCC BY 4.0Inorganics

Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages

  • Amina Benchohra
  • Simon Séjourné
  • Antoine Labrunie
  • Liam Miller
  • Enzo Charbonneau
  • Vincent Carré
  • Frédéric Aubriet
  • Magali Allain
  • Marc Sallé
  • Sébastien Goeb
Open at sourcePDFDOICite

Abstract

Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M2), afforded three chiral face-rotating stereoisomer polyhedra (M6L2). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M6L2), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.

Related

  1. Framework-Templated Single Clathrate Hydrate Cages in Metal–Organic Frameworks
    Jihan Kim
    ChemRxivPreprintLicence not statedGeneral chemistryChemRxiv
  2. Encapsulation of f-block elements in borocarbide cages: Synthesis of a magnetic NdB3C3 clathrate
    Mads F. Hansen, Tiange Bi, Aldo Raeliarijaona +6
    ChemRxivPreprintLicence not statedGeneral chemistryChemRxiv
  3. Mixed thiolate/alkoxide antimony cages for stable reversed-bilayer vesicle self-assembly
    Lina M. Delgado, Olivia H. Villanueva, Shiva Moaven +3
    ChemRxivPreprintCC BYFull textOrganic chemistryChemRxiv
  4. Pnictogen-Bond-Directed Self-Assembly of Sb and As Cages Enables Partitioning of Organic Reaction Media.
    Olivia H Villanueva, Lina M Delgado, Lauren A Moran +3
    Langmuir : the ACS journal of surfaces and colloidsPeer-reviewedCC BY-NC-NDFull textOrganic chemistryEurope PMC
  5. Directed Surface Immobilization of Coordination Cages for Host-Guest Studies.
    Samantha Muhring-Salamone, Lisa Schardt, Shota Hasegawa +5
    Langmuir : the ACS journal of surfaces and colloidsPeer-reviewedCC BYFull textOrganic chemistryEurope PMC

Cite

BibTeXRIS
BibTeX
@article{benchohra2026controlling,
  title = {{Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages}},
  author = {Amina Benchohra and Simon Séjourné and Antoine Labrunie and Liam Miller and Enzo Charbonneau and Vincent Carré and Frédéric Aubriet and Magali Allain and Marc Sallé and Sébastien Goeb},
  journal = {Inorganics},
  year = {2026},
  month = sep,
  doi = {10.3390/inorganics10070103},
  url = {https://cnrs.hal.science/hal-03773676v1},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages
AU  - Amina Benchohra
AU  - Simon Séjourné
AU  - Antoine Labrunie
AU  - Liam Miller
AU  - Enzo Charbonneau
AU  - Vincent Carré
AU  - Frédéric Aubriet
AU  - Magali Allain
AU  - Marc Sallé
AU  - Sébastien Goeb
PY  - 2026
DA  - 2026/09/02
JO  - Inorganics
DO  - 10.3390/inorganics10070103
UR  - https://cnrs.hal.science/hal-03773676v1
AB  - Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M2), afforded three chiral face-rotating stereoisomer polyhedra (M6L2). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M6L2), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.
SN  - 2304-6740
ER  -