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Peer-reviewedCC BY 4.0Scientific Reports

Multi-resonant Ag–AZO based PCF-SPR sensor for highly sensitive ethylene glycol detection in industrial applications

Abstract

A dual-plasmonic Surface Plasmon Resonance (SPR) based Photonic Crystal Fiber (PCF) sensor incorporating silver (Ag) and aluminum-doped zinc oxide (AZO) layers is proposed for high-precision detection of ethylene glycol (EG) concentration. The PCF structure, designed using the Finite Element Method (FEM) in COMSOL Multiphysics, employs two plasmonic materials that generate multiple confinement-loss peaks, enabling enhanced detection over a broad spectral range. The novelty of the proposed configuration lies in exploiting the distinct plasmonic dispersion characteristics of Ag and AZO within a single PCF platform to support multiple spectrally separated resonance modes, including AZO-dominated, Ag-dominated, and hybrid Ag–AZO resonances. EG concentration is quantified through its corresponding refractive index variation, allowing accurate monitoring across 0–80% EG by weight. The sensor achieves an ultra-high wavelength sensitivity of 117,300 nm/RIU, an amplitude sensitivity of 2339 RIU ⁻¹ , a detection resolution of 8.53 × 10 ⁻⁷ RIU, along with excellent linearity of 0.99808. A high figure of merit of 690 RIU ⁻¹ further confirms the superior detection sharpness enabled by the Ag–AZO dual-layer design. Owing to its compact geometry, multi-resonant response, and high sensitivity, the proposed SPR-PCF sensor shows promising performance for precise EG concentration monitoring in industrial and pharmaceutical applications where accurate concentration control is required.

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BibTeX
@article{munim2026multiresonant,
  title = {{Multi-resonant Ag–AZO based PCF-SPR sensor for highly sensitive ethylene glycol detection in industrial applications}},
  author = {Nasir M. Munim and Mohammad Ataul Karim and Tahmina Tabassum Treena},
  journal = {Scientific Reports},
  year = {2026},
  month = sep,
  doi = {10.1038/s41598-026-74120-3},
  url = {https://www.nature.com/articles/s41598-026-74120-3},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Multi-resonant Ag–AZO based PCF-SPR sensor for highly sensitive ethylene glycol detection in industrial applications
AU  - Nasir M. Munim
AU  - Mohammad Ataul Karim
AU  - Tahmina Tabassum Treena
PY  - 2026
DA  - 2026/09/30
JO  - Scientific Reports
DO  - 10.1038/s41598-026-74120-3
UR  - https://www.nature.com/articles/s41598-026-74120-3
AB  - A dual-plasmonic Surface Plasmon Resonance (SPR) based Photonic Crystal Fiber (PCF) sensor incorporating silver (Ag) and aluminum-doped zinc oxide (AZO) layers is proposed for high-precision detection of ethylene glycol (EG) concentration. The PCF structure, designed using the Finite Element Method (FEM) in COMSOL Multiphysics, employs two plasmonic materials that generate multiple confinement-loss peaks, enabling enhanced detection over a broad spectral range. The novelty of the proposed configuration lies in exploiting the distinct plasmonic dispersion characteristics of Ag and AZO within a single PCF platform to support multiple spectrally separated resonance modes, including AZO-dominated, Ag-dominated, and hybrid Ag–AZO resonances. EG concentration is quantified through its corresponding refractive index variation, allowing accurate monitoring across 0–80% EG by weight. The sensor achieves an ultra-high wavelength sensitivity of 117,300 nm/RIU, an amplitude sensitivity of 2339 RIU ⁻¹ , a detection resolution of 8.53 × 10 ⁻⁷ RIU, along with excellent linearity of 0.99808. A high figure of merit of 690 RIU ⁻¹ further confirms the superior detection sharpness enabled by the Ag–AZO dual-layer design. Owing to its compact geometry, multi-resonant response, and high sensitivity, the proposed SPR-PCF sensor shows promising performance for precise EG concentration monitoring in industrial and pharmaceutical applications where accurate concentration control is required.
SN  - 2045-2322
ER  -