Facile Synthesis of Zn/Fe@C Photocatalyst for Visible-Light-Driven H2O2 Production and Pollutant Degradation
4 affiliations
- 1Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
- 2Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
- 3Nanotechnology Research Unit, College of Science, Jazan University, P.O. Box. 114, Jazan 45142, Saudi Arabia
- 4Department of Physical Sciences, Chemistry Division, College of Science, Jazan University, P.O. Box. 114, Jazan 45142, Saudi Arabia
Abstract
A zinc oxide–iron oxide embedded graphitic carbon (Zn/Fe@C) photocatalyst was successfully synthesized by pyrolysis of chitosan hydrogel impregnated with zinc and iron salts. Structural characterization confirmed the formation of a predominantly crystalline, multi-phase oxide system, while morphological analysis revealed a rough and heterogeneous surface with aggregated features. Elemental analysis further verified the incorporation of Zn and Fe species within the graphitic carbon matrix. The photocatalytic performance of the prepared material was evaluated through hydrogen peroxide (H2O2) production and dye degradation under simulated solar irradiation. Zn/Fe@C exhibited superior H2O2 production performance, achieving a maximum concentration of 2.9 mmol L−1. The use of different alcohols as sacrificial agents revealed that 2-propanol significantly enhanced H2O2 generation, while increasing catalyst loading improved H2O2 production due to the availability of additional active sites. In dye degradation experiments, the photocatalyst demonstrated high efficiency toward the removal of representative organic dyes, including methylene blue, methyl orange, and acridine orange, with the latter showing the highest degradation efficiency of 96.6%. The effect of catalyst loading indicated that lower dosages resulted in optimal performance, which was attributed to improved light penetration and reduced aggregation effects. Control experiments confirmed that photocatalysis was the dominant mechanism over adsorption. Furthermore, increasing the metal precursor concentration enhanced photocatalytic activity, while the material maintained good reusability over multiple cycles. Furthermore, Zn/Fe@C was compared with Cu/Fe@C and Cu/Zne@C where Zn/Fe@C exhibited superior performance among the investigated photocatalysts in H2O2 production and dye degradation. Overall, the results highlight the potential of the developed Zn/Fe@C photocatalyst as a promising material for sustainable H2O2 production and efficient degradation of organic pollutants.
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BibTeX
@article{basalam2026facile,
title = {{Facile Synthesis of Zn/Fe@C Photocatalyst for Visible-Light-Driven H2O2 Production and Pollutant Degradation}},
author = {Osama K. Basalam and Majed S. Almalki and Muhammad Nadeem Arshad and Sher Bahadar Khan and Kalsoom Akhtar and Nujud Maslamani and Esraa M. Bakhsh},
journal = {Nanomaterials (Basel, Switzerland)},
year = {2026},
month = oct,
doi = {10.3390/nano16191255},
url = {https://europepmc.org/article/PMC/PMC13667153},
note = {CC BY},
}
RIS
TY - JOUR
TI - Facile Synthesis of Zn/Fe@C Photocatalyst for Visible-Light-Driven H2O2 Production and Pollutant Degradation
AU - Osama K. Basalam
AU - Majed S. Almalki
AU - Muhammad Nadeem Arshad
AU - Sher Bahadar Khan
AU - Kalsoom Akhtar
AU - Nujud Maslamani
AU - Esraa M. Bakhsh
PY - 2026
DA - 2026/10/01
JO - Nanomaterials (Basel, Switzerland)
DO - 10.3390/nano16191255
UR - https://europepmc.org/article/PMC/PMC13667153
AB - A zinc oxide–iron oxide embedded graphitic carbon (Zn/Fe@C) photocatalyst was successfully synthesized by pyrolysis of chitosan hydrogel impregnated with zinc and iron salts. Structural characterization confirmed the formation of a predominantly crystalline, multi-phase oxide system, while morphological analysis revealed a rough and heterogeneous surface with aggregated features. Elemental analysis further verified the incorporation of Zn and Fe species within the graphitic carbon matrix. The photocatalytic performance of the prepared material was evaluated through hydrogen peroxide (H2O2) production and dye degradation under simulated solar irradiation. Zn/Fe@C exhibited superior H2O2 production performance, achieving a maximum concentration of 2.9 mmol L−1. The use of different alcohols as sacrificial agents revealed that 2-propanol significantly enhanced H2O2 generation, while increasing catalyst loading improved H2O2 production due to the availability of additional active sites. In dye degradation experiments, the photocatalyst demonstrated high efficiency toward the removal of representative organic dyes, including methylene blue, methyl orange, and acridine orange, with the latter showing the highest degradation efficiency of 96.6%. The effect of catalyst loading indicated that lower dosages resulted in optimal performance, which was attributed to improved light penetration and reduced aggregation effects. Control experiments confirmed that photocatalysis was the dominant mechanism over adsorption. Furthermore, increasing the metal precursor concentration enhanced photocatalytic activity, while the material maintained good reusability over multiple cycles. Furthermore, Zn/Fe@C was compared with Cu/Fe@C and Cu/Zne@C where Zn/Fe@C exhibited superior performance among the investigated photocatalysts in H2O2 production and dye degradation. Overall, the results highlight the potential of the developed Zn/Fe@C photocatalyst as a promising material for sustainable H2O2 production and efficient degradation of organic pollutants.
SN - 2079-4991
ER -