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PreprintCC BY 4.0arXiv

Diffusion of charged rods across 3D varying section channels

Abstract

We analyze the transport of rod-like particles by diffusion and drift in a three-dimensional channel with varying circular or elliptic cross section. Applying the Fick-Jacobs approximation to the transport equation of the particles' probability distribution, we derive an effective one-dimensional substitute model and the associated free energy profile. Our results show that the data for the mean first passage time of rods, once expressed as a function of the effective free energy barrier, collapse onto the same master curve as obtained for point or spherical particles. The observed universality provides a simple framework for predicting transport times of anisotropic particles in confined geometries without resolving the full multidimensional dynamics.

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BibTeX
@misc{ray2026diffusion,
  title = {{Diffusion of charged rods across 3D varying section channels}},
  author = {N. Ray and A. Semkiv and J. Harting and P. Malgaretti},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.29427},
  eprint = {2609.29427},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.29427},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Diffusion of charged rods across 3D varying section channels
AU  - N. Ray
AU  - A. Semkiv
AU  - J. Harting
AU  - P. Malgaretti
PY  - 2026
DA  - 2026/09/24
PB  - arXiv
DO  - 10.48550/arxiv.2609.29427
UR  - https://arxiv.org/abs/2609.29427
AB  - We analyze the transport of rod-like particles by diffusion and drift in a three-dimensional channel with varying circular or elliptic cross section. Applying the Fick-Jacobs approximation to the transport equation of the particles' probability distribution, we derive an effective one-dimensional substitute model and the associated free energy profile. Our results show that the data for the mean first passage time of rods, once expressed as a function of the effective free energy barrier, collapse onto the same master curve as obtained for point or spherical particles. The observed universality provides a simple framework for predicting transport times of anisotropic particles in confined geometries without resolving the full multidimensional dynamics.
ER  -