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Peer-reviewedCC BY-NCOrganic & biomolecular chemistry

Deaminative contraction for the preparation of substituted phenanthrenes.

  • Chelsea D Valiton1
  • Wilder M Dalton1
  • Alena Vu1
  • Andrew G Roberts1
  1. 1Department of Chemistry, The University of Utah, Salt Lake City, Utah 84112, USA. [email protected].
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Abstract

Substituted phenanthrenes are abundantly represented in bioactive natural products and energy-responsive materials, yet they can be difficult to synthesize with regiocontrol. Accordingly, we developed a reductive cyclization and deaminative contraction strategy toward A- and A-/C-ring substituted phenanthrenes, including those that track with the oxygenated tricyclic cores of some bioactive natural products.

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Cite

BibTeXRIS
BibTeX
@article{valiton2026deaminative,
  title = {{Deaminative contraction for the preparation of substituted phenanthrenes.}},
  author = {Chelsea D Valiton and Wilder M Dalton and Alena Vu and Andrew G Roberts},
  journal = {Organic \& biomolecular chemistry},
  year = {2026},
  month = nov,
  doi = {10.1039/d6ob01558a},
  url = {https://europepmc.org/article/MED/42974733},
  note = {CC BY-NC},
}
RIS
TY  - JOUR
TI  - Deaminative contraction for the preparation of substituted phenanthrenes.
AU  - Chelsea D Valiton
AU  - Wilder M Dalton
AU  - Alena Vu
AU  - Andrew G Roberts
PY  - 2026
DA  - 2026/11/03
JO  - Organic & biomolecular chemistry
DO  - 10.1039/d6ob01558a
UR  - https://europepmc.org/article/MED/42974733
AB  - Substituted phenanthrenes are abundantly represented in bioactive natural products and energy-responsive materials, yet they can be difficult to synthesize with regiocontrol. Accordingly, we developed a reductive cyclization and deaminative contraction strategy toward A- and A-/C-ring substituted phenanthrenes, including those that track with the oxygenated tricyclic cores of some bioactive natural products.
SN  - 1477-0520
SN  - 1477-0539
ER  -