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Peer-reviewedCC BY 4.0ARKIVOC - Online Journal of Organic Chemistry

Solid-phase cleavage by a thermal retro-Diels-Alder reaction: preparation of a small β-substituted α,β-ethylenic aldehydes library

  • Sébastien Albert
  • Luis Blanco
  • Sandrine Deloisy
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Abstract

Michael addition of heteroatom and carbon centered nucleophiles on 7-oxanorborna-2,5-diene-2-carboxaldehyde derivatives followed by a retro-Diels-Alder reaction allowed liquid- and solid-phase synthesis of a small library of alpha,beta-unsaturated aldehydes. Emphasis should be put on the purity of the enals prepared on solid support, a purification step was not necessary.

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Cite

BibTeXRIS
BibTeX
@article{albert2026solidphase,
  title = {{Solid-phase cleavage by a thermal retro-Diels-Alder reaction: preparation of a small β-substituted α,β-ethylenic aldehydes library}},
  author = {Sébastien Albert and Luis Blanco and Sandrine Deloisy},
  journal = {ARKIVOC - Online Journal of Organic Chemistry},
  year = {2026},
  month = oct,
  doi = {10.3998/ark.5550190.0010.d07},
  url = {https://hal.science/hal-05841178v1},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Solid-phase cleavage by a thermal retro-Diels-Alder reaction: preparation of a small β-substituted α,β-ethylenic aldehydes library
AU  - Sébastien Albert
AU  - Luis Blanco
AU  - Sandrine Deloisy
PY  - 2026
DA  - 2026/10/27
JO  - ARKIVOC - Online Journal of Organic Chemistry
DO  - 10.3998/ark.5550190.0010.d07
UR  - https://hal.science/hal-05841178v1
AB  - Michael addition of heteroatom and carbon centered nucleophiles on 7-oxanorborna-2,5-diene-2-carboxaldehyde derivatives followed by a retro-Diels-Alder reaction allowed liquid- and solid-phase synthesis of a small library of alpha,beta-unsaturated aldehydes. Emphasis should be put on the purity of the enals prepared on solid support, a purification step was not necessary.
SN  - 1551-7004
SN  - 1551-7012
ER  -