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From a three-fluid junction to Young's law: Constitutive and rigid-support limits of wetting

Abstract

Young's law on a rigid solid and the Neumann balance at a three-fluid junction describe different admissible motions. We connect them through an ordered continuum construction. An affine viscoelastic third phase first acquires permanent deformation memory in the no-relaxation limit at fixed modulus. Independently specified material-surface laws distinguish surface free energy from mechanical surface stress. On the deformable support, displacement of solid material and migration of the wet-dry partition give separate equilibrium conditions. Stiffening an anchored support suppresses displacement at a fixed macroscopic observation distance but leaves reversible migration possible. The surviving variation gives Young's law; the constrained mechanics remains as a reaction carrying normal and, in general, tangential capillary loads. Two complementary results substantiate this reduction. A clamped finite-strain model with circular liquid interfaces yields uniform convergence of reduced energies and recovery of the spatial Young angle for global almost minimisers. A separate quadratic half-space model gives convergence of stationary migration derivatives and a nonzero limiting traction distribution. The results explain how a local Neumann-like ridge can coexist with a Young angle measured against the distant wall, while distinguishing geometric convergence from the control of migration and reaction forces.

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BibTeX
@misc{bothe2026from,
  title = {{From a three-fluid junction to Young's law: Constitutive and rigid-support limits of wetting}},
  author = {Dieter Bothe},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.31672},
  eprint = {2609.31672},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.31672},
}
RIS
TY  - UNPB
TI  - From a three-fluid junction to Young's law: Constitutive and rigid-support limits of wetting
AU  - Dieter Bothe
PY  - 2026
DA  - 2026/09/15
PB  - arXiv
DO  - 10.48550/arxiv.2609.31672
UR  - https://arxiv.org/abs/2609.31672
AB  - Young's law on a rigid solid and the Neumann balance at a three-fluid junction describe different admissible motions. We connect them through an ordered continuum construction. An affine viscoelastic third phase first acquires permanent deformation memory in the no-relaxation limit at fixed modulus. Independently specified material-surface laws distinguish surface free energy from mechanical surface stress. On the deformable support, displacement of solid material and migration of the wet-dry partition give separate equilibrium conditions. Stiffening an anchored support suppresses displacement at a fixed macroscopic observation distance but leaves reversible migration possible. The surviving variation gives Young's law; the constrained mechanics remains as a reaction carrying normal and, in general, tangential capillary loads. Two complementary results substantiate this reduction. A clamped finite-strain model with circular liquid interfaces yields uniform convergence of reduced energies and recovery of the spatial Young angle for global almost minimisers. A separate quadratic half-space model gives convergence of stationary migration derivatives and a nonzero limiting traction distribution. The results explain how a local Neumann-like ridge can coexist with a Young angle measured against the distant wall, while distinguishing geometric convergence from the control of migration and reaction forces.
ER  -