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Peer-reviewedCC BY 4.0Journal of Applied Physics

Mn3−xZnxTa₂O₈: Inducing multiferroelectricity in a linear magnetoelectric material

Abstract

Zn for Mn substitution has been studied in the linear magnetoelectric Mn₃Ta₂O₈. Although limited, the Zn substitution has a strong impact on the magnetic properties, inducing a spectacular, narrow, and high magnetic susceptibility peak at the antiferromagnetic transition temperature TN for Mn2.5Zn0.5Ta₂O₈. A concomitant change in the electric behavior is observed with a magnetodielectric effect below TN. Also, notably, in addition to the linear magnetoelectricity found at lower temperatures, a spontaneous polarization is induced over a limited temperature range below TN. The sensitivity of the Mn₃Ta₂O₈ magnetoelectric properties is interpreted as a result of a modification of Mn–O–Mn exchange interactions between the Mn²⁺

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BibTeX
@article{maignan2026mn3xznxta₂o₈,
  title = {{Mn3−xZnxTa₂O₈: Inducing multiferroelectricity in a linear magnetoelectric material}},
  author = {Antoine Maignan and Fabien Veillon and Christine Martin},
  journal = {Journal of Applied Physics},
  year = {2026},
  month = oct,
  doi = {10.1063/5.0294141},
  url = {https://hal.science/hal-05612296v1},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Mn3−xZnxTa₂O₈: Inducing multiferroelectricity in a linear magnetoelectric material
AU  - Antoine Maignan
AU  - Fabien Veillon
AU  - Christine Martin
PY  - 2026
DA  - 2026/10/29
JO  - Journal of Applied Physics
DO  - 10.1063/5.0294141
UR  - https://hal.science/hal-05612296v1
AB  - Zn for Mn substitution has been studied in the linear magnetoelectric Mn₃Ta₂O₈. Although limited, the Zn substitution has a strong impact on the magnetic properties, inducing a spectacular, narrow, and high magnetic susceptibility peak at the antiferromagnetic transition temperature TN for Mn2.5Zn0.5Ta₂O₈. A concomitant change in the electric behavior is observed with a magnetodielectric effect below TN. Also, notably, in addition to the linear magnetoelectricity found at lower temperatures, a spontaneous polarization is induced over a limited temperature range below TN. The sensitivity of the Mn₃Ta₂O₈ magnetoelectric properties is interpreted as a result of a modification of Mn–O–Mn exchange interactions between the Mn²⁺
SN  - 0021-8979
SN  - 1089-7550
ER  -